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Nanosecond electric pulse-induced ultrafast piezoelectric responses in Co3+ substituted BiFeO3 epitaxial thin films

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Author(s)
Unithrattil, Sanjith; Min, Taewon; Anoop, Gopinathan; Lee, Jun Young; Kim, Tae Yeon; Samanta, Shibnath; Qi, Yubo; Zhang, Jiahao; Hwang, Seung Hyun; Lee, Hyeon Jun; Guo, Kun; Lee, Su Yong; Imai, Yasuhiko; Sakata, Osami; Shimizu, Keisuke; Shigematsu, Kei; Hojo, Hajime; Yao, Kui; Azuma, Masaki; Lee, Jaekwang; Rappe, Andrew M.; Jo, Ji Young
Type
Article
Citation
Current Applied Physics, v.70, pp.76 - 80
Issued Date
2025-02
Abstract
Understanding the ultra-fast dynamics of ferroelectric materials is essential for advancing the development of next-generation high speed electronic and photonic devices. Here, the ultrafast piezoelectric response of cobalt-substituted BiFeO3 (BiFe1-xCoxO3) with x = 0.15, consisting of morphotropic phase boundary of monoclinic MC and MA –type phases is investigated. The real-time piezoelectric response in (001)-oriented BiFe0.85Co0.15O3 (BFCO) epitaxial thin film was monitored using the time-resolved X-ray microdiffraction technique under an applied electric field with pulse widths 70 ns and 100 ns. The BFCO thin film yielded a high piezoelectric strain of approximately 0.53 % along [001] direction, with a giant c/a ratio (∼1.26) at an electric field of 1.3 MV/cm and a pulse width of 100 ns, with a piezoelectric coefficient (d33) of 40 pm/V. This finding is an important step towards the development of a high performance lead-free piezoelectric material for ultrafast operations in advanced technological applications. © 2024 Korean Physical Society
Publisher
Elsevier B.V.
ISSN
1567-1739
DOI
10.1016/j.cap.2024.11.012
URI
https://scholar.gist.ac.kr/handle/local/9068
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