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Polymorphing Hydrogels Regulated by Photo-reactive DNA Cross-links

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Author(s)
Roh, Junho; Park, Seongjun; Kim, Hoeseong; Kim, Woojin; Kim, Jinho; Park, Cheolheon; Choi, Hansol; Song, Seowoo; Choi, Eunjin; Choi, Yeongjae
Type
Article
Citation
Advanced Materials, v.37, no.5
Issued Date
2025-02
Abstract
Polymorphing hydrogels can morph into another structure on demand with reprogrammable features. This concept extends the degree of morphing beyond that of traditional shape-morphing hydrogels, which predetermine their morphing capabilities at the fabrication stage. However, current polymorphing hydrogels face limitations due to the need for complex, non-sustained responsiveness or additional chemical steps for reconfigurable morphing. Here, photo-reactive DNA-cross-linked polymorphing hydrogels are presented that enable polymorphing under patterned light. The photo-reactive DNA cross-links act as a regulator in changing the shapes of the hydrogels by adjusting the lengths of the cross-links depending on the wavelength of light, which allows precise and dynamic morphing in a programmable way through a one-pot reaction. The high programmability involving spatiotemporal controllability and reprogrammable features offers advanced solutions for multifunctional soft machines and applications requiring complex processes. © 2024 Wiley-VCH GmbH.
Publisher
John Wiley and Sons Inc
ISSN
0935-9648
DOI
10.1002/adma.202414648
URI
https://scholar.gist.ac.kr/handle/local/9066
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