Photoinduced surface deformations on azobenzene polymer films

Abstract

Laser-induced surface deformation and surface relief grating formation at different intensity levels on azobenzene-functionalized polymer films were investigated. The surface deformation profile induced by a Gaussian laser beam at low intensities reveals strong polarization dependence and establishes that an optical-field component in the direction of the optical-field gradient is essential for this deformation process. A theoretical analysis based on the optical-field gradient force model is presented to account for the deformation behavior at low intensities. In the higher-intensity regime, however, a different mechanism is found to dominate the surface deformation process. Simultaneous formation of two different types of topographic gratings is observed in a two-beam interference experiment. The phase relationship between these surface relief gratings and the interference intensity pattern was deduced based on the results from the single-beam experiments. The erasing behaviors of the two distinct surface relief gratings were experimentally investigated to highlight the two mechanisms involved in these grating recordings. (C) 1999 American Institute of Physics. [S0021-8979(99)03920-1].