Development of an Aerosol Focusing-Laser Induced Breakdown Spectroscopy (Aerosol Focusing-LIBS) for Determination of Fine and Ultrafine Metal Aerosols

Abstract

An Aerosol Focusing-Laser Induced Breakdown Spectroscopy (Aerosol Focusing-LIBS) with a sheath air focusing and an aerodynamic lens focusing was developed to determine elemental composition of fine and ultrafine metal aerosols. Data showed that with a sheath air focusing, the LIBS qualitatively detected various metals (Al, Ca, Cd, Cr, Cu, K, Mg, Na, Ni, Zn) in submicrometer to micrometer aerosols, but that detection of ultrafine particles smaller than 100 nm was not successful due to weak intensity of emitted light. Also, the hitting rate was so low for particles at low number concentration and the single particle detection approach was only valid when aerosol loading is low. Thus, we concentrated aerosols on to a collection substrate by using the aerodynamic lens focusing system, resulting in the strong emission light from the generated plasma even for nanoparticles and the better quantification performance by the LIBS. We found the linear relationship between LIBS signal response and metal mass concentration. For example, as Cu metal concentration increased, peak area of LIBS emission line for Cu increased. The resulting correlation coefficient was 0.94 and the LOD for Cu mass concentration was found to be similar to 80 ng/m3, which can be further lowered by extending current collection time (similar to 5 min). A similar linear relationship was found for Cd and Ni ultrafine metal aerosols. We also successfully detected internally mixed metal aerosols. When particles were collected on a substrate with the aerodynamic lens for 5 min prior to analysis of the deposit it was possible to analyze particles as small as 60 nm.