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A high-pressure-induced dense CO overlayer on a Pt(111) surface: a chemical analysis using in situ near ambient pressure XPS

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Author(s)
Toyoshima, Ryo; Yoshida, Masaaki; Monya, Yuji; Suzuki, Kazuma; Amemiya, Kenta; Mase, Kazuhiko; Mun, Bongjin Simon; Kondoh, Hiroshi
Type
Article
Citation
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.16, no.43, pp.23564 - 23567
Issued Date
2014-10
Abstract
We investigated the high-density CO adsorption phase formed on a Pt(111) surface when exposed to CO gas of pressure ranging from UHV to 100 mTorr using near-ambient-pressure (NAP)-XPS. Combined results from the NAP-XPS measurements and DFT calculations reveal the adsorption structure of CO molecules in the dense CO overlayer, which is stable under realistic conditions.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1463-9076
DOI
10.1039/c4cp04318a
URI
https://scholar.gist.ac.kr/handle/local/15021
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