Nonlinear absorption and optical damage threshold of carbon-based nanostructured material embedded in a protein

Abstract

Physical processes in laser-matter interaction used to be determined by generation of fast electrons resulting from efficient conversion of the absorbed laser radiation. Composite materials offer the possibility to control the absorption by choice of the host material and dopants. Reported here strong absorption of ultrashort laser pulse in a composite carbon-based nanomaterial including single-walled carbon nanotubes (SWCNTs) or multilayer graphene was measured in the intensity range between 10(12) and 10(16) W cm(-2). A protein (lysozyme) was used as the host. The maximum absorption of femtosecond laser pulse has reached 92-96 %. The optical damage thresholds of the coatings were registered at an intensity of (1.1 +/- 0.5) x 10(13) W cm(-2) for the embedded SWCNTs and at (3.4 +/- 0.3) x 10(13) W cm(-2) for the embedded graphene. Encapsulated variant of the dispersed nanomaterial was investigated as well. It was found that supernatant protein in the coating material tends to dominate the absorption process, independently of the embedded nanomaterial. The opposite was observed for the encapsulated material.