OAK

A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor

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Author(s)
Min, Kyung Eun; Washenfelder, R. A.; Dube, W. P.; Langford, A. O.; Edwards, P. M.; Zarzana, K. J.; Stutz, J.; Lu, K.; Rohrer, F.; Zhang, Y.; Brown, S. S.
Type
Article
Citation
Atmospheric Measurement Techniques, v.9, no.2, pp.423 - 440
Issued Date
2016-02
Abstract
We describe a two-channel broadband cavity enhanced absorption spectrometer (BBCEAS) for aircraft measurements of glyoxal (CHOCHO), methylglyoxal (CH3COCHO), nitrous acid (HONO), nitrogen dioxide (NO2), and water (H2O). The instrument spans 361-389 and 438-468 nm, using two light-emitting diodes (LEDs) and a single grating spectrometer with a charge-coupled device (CCD) detector. Robust performance is achieved using a custom optical mounting system, high-power LEDs with electronic on/off modulation, high-reflectivity cavity mirrors, and materials that minimize analyte surface losses. We have successfully deployed this instrument during two aircraft and two ground-based field campaigns to date. The demonstrated precision (2 sigma) for retrievals of CHOCHO, HONO and NO2 are 34, 350, and 80 parts per trillion (pptv) in 5 s. The accuracy is 5.8, 9.0, and 5.0%, limited mainly by the available absorption cross sections.
Publisher
COPERNICUS GESELLSCHAFT MBH
ISSN
1867-1381
DOI
10.5194/amt-9-423-2016
URI
https://scholar.gist.ac.kr/handle/local/14384
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