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GIST Scholar College of Natural Sciences Department of Physics and Photon Science 1. Journal Articles

Catalytic CO oxidation over Pd70Au30(111) alloy surfaces: spectroscopic evidence for Pd ensemble dependent activity

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Author(s)
Toyoshima, Ryo; Hiramatsu, Nana; Yoshida, Masaaki; Amemiya, Kenta; Mase, Kazuhiko; Mun, Bongjin Simon; Kondoh, Hiroshi
Type
Article
Citation
Chemical Communications, v.53, no.94, pp.12657 - 12660
Issued Date
2017-12
Abstract
Catalytic CO oxidation over Pd(111) and Pd70Au30(111) surfaces was investigated by in situ spectroscopic observations to understand the alloying effect. The reaction behaviour on Pd70Au30(111) is greatly different from that on Pd(111). Pd monomer and dimer ensembles can act as active centers, whereas triangular-shaped trimers and larger ensembles are inactive.
Publisher
Royal Society of Chemistry
ISSN
1359-7345
DOI
10.1039/c7cc06809c
URI
https://scholar.gist.ac.kr/handle/local/13491
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