Face-on oriented thermolabile Boc-isoindigo/thiophenes small molecules: From synthesis to OFET performance

Abstract

A new series of protected isoindigo (ID) based solution processable donor-acceptor type of small molecules was synthesized. Tert-butoxycarbonyl (t-Boc) substituted isoindigo is used as the acceptor unit and oligothiophene derivatives as the donor units. Thermal decarboxylation of small molecules films at 200 degrees C eliminated the t-Boc side groups. The cleavage of the protecting group formed a variety of N-H center dot center dot center dot center dot center dot O=C hydrogen bonding across the lactam structures of the isoindigo. The molecular orientation during the thermal decarboxylation of ID-Boc to ID-H was examined using X-ray diffraction and atomic force microscopy. The H-bonding formation and its impact on the optical, thermal, electrochemical and ambipolar behavior were investigated.